Abstract
4-xlorofenoksisirka kislota va mis (II) sulfat asosida kompleks birikma [Cu(4-D)2(H2O)2] olindi. Kompleks rentgen strukturaviy analizi, kompleks tuzilishini maqbullashtirgan holda DFT hisoblashlari va Xirshfeld yuzasi tahlilini ham o‘tkazildi. Birikma tarkibidagi 4-D ning fenoksi guruhidagi kislorod va markaziy atom mis orasidagi masofa farqi Yan-Tellar effekti bilan tushuntiriladi. Xirshfeld yuzasi tahlili barmoq izlari sohasi H···H ta’sirlarning yuza ta’sirlari orasida eng ko‘p hissa qo‘shishini ko‘rsatadi, bu esa kislorod atomlari dominantlik qiladigan molekulalar uchun kutilgan holatdir.
References
Ghoshdastidar A., Treatment of organophosphorus insecticides and phenoxyacetic acid herbicides using membrane bioreactor technology // MS thesis, Acadia University, Spring Convocation. -2012. –P. 169.
Krieger R., Hayes’ Handbook of Pesticide Toxicology, third ed., // Academic Press. -2010. –P. 58-65.
Ma, D.-Y., Guo, H.-F., Dong, J. & Xu, J. Unusual self-assembled 1D tape of tetramers and water–nitrate clusters trapped in a zinc(II) complex: Synthesis, characterization, luminescence and catalytic properties //J. Mol. Struct. -2013. –P. 1054–1055,
Li L., Diaoa K., Ding Y. & Yin X. Hydrothermal Synthesis, Crystal Structure of Five Novel Complexes Based on 4-Chlorophenyloxyacetic Acid, Molecular Crystals and Liquid Crystals // Mol. Cryst. Liq. Cryst. 575. -2013 –P. 173–187.
A. Drzewiecka-Antonik et al. Structural characterization and cytotoxic evaluation of Cu(II), Co(II) and Ni(II) complexes with herbicide 4-chloro-2-methylphenoxyacetic acid // Polyhedron. 165 . -2019.–P. 86–96.
Sun Y., Wang Z., Zhang H., Cao Y., Zhang S., Chen Y., Huang Ch. & Yu X. Self-assembly of three novel mixed-ligand coordination polymers: Formation of 2-D grids, 1-D chains and ladders and crystal band structure // Inorg. Chim. Acta. 360. -2007. –P. 2565–2572.
Liwporncharoenvong, T. & Luck, R. L. Tetrakis(l-4-chlorophenoxyacetato-j2 O,O)- dimolybdenum(II)//Acta Cryst. 61. -2005. –P. 1191–1193
Jin, Sh., Liu, H., Chen, G., An, Z., Lou, Y., Huang, K. & Wang, D Syntheses and crystal structures of copper(II), zinc(II) and cadmium(II) complexes containing pyridine, quinoline and 2-methylquinoline// Polyhedron. 95. -2015. –P. 91–107. http://dx.doi.org/10.1016/j.poly.2015.04.017
Hanwell, M.D., Curtis, D.E., Lonie, D.C., Vandermeersch, T., Zurek, E., & Hutchison, G.R. 2012, J Cheminform, 4:17.
Neese F. ORCA Program system // Comput. Mol. Sci. 2.-2012. –P.73.
Lu, T., & Chen, F.W. Multiwfn: A multifunctional wavefunction analyzer// J. Comp.Chem., 2. -2012. –P. 15
Humphrey, W. Dalke, A., & Schulten K. “VMD - Visual Molecular Dynamics”// J. Molec. Graphics. vol. 14. -1996. –P. 33-38
Alimnazarov B.Kh., Ashurov J.M., Eshimbetov A.G.,. Turaev Kh. Kh, Ibragimov B.T. Electronic structure of diaquabis(p-chlorophenoxyacetato) copper(II) complex by DFT method// ISJ Theoretical & Applied Science. 10 (102). -2021. –P. 964-968.
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