Vol. 2 No. 5 (2024), Articles
Vol. 2 No. 5 (2024)

QUANTUM CHEMICAL ANALYSIS OF REACTIVITY OF DITHIZONE (DIPHENYLTHIOCARBAZONE) REAGENT

Articles
Published 2024-05-28
Yuldashova S.G
Termez State University, Barkamol Avlod Street 43, Termez, Uzbekistan
Jumayeva Z.E
Termez State University, Barkamol Avlod Street 43, Termez, Uzbekistan,
Muzaffarova N.Sh
Department of Medical and Biological Chemistry, Termiz branch of the Tashkent Medical Academy
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Keywords

dithizone, extraction method, Khondzha, lead and zinc metal ions,

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QUANTUM CHEMICAL ANALYSIS OF REACTIVITY OF DITHIZONE (DIPHENYLTHIOCARBAZONE) REAGENT. (2024). Journal of Universal Science Research, 2(5), 765-774. https://universalpublishings.com/index.php/jusr/article/view/6008
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Abstract

This paper studies methods of lead and zinc metal ions extraction by dithizone from Khondzha wastewater samples. Inorganic metals or ions can act back with dithizone to produce colourful coordination. The dithizone reagent is highly sensitive to the presence of heavy metals such as lead (Pb) and zinc (Zn) as designated in this study. Inorganic metals or ionic can react with dithizone to produce coloured coordination compounds. As a result of studying the "composition-structure-property" system in chemical compounds, it is possible to theoretically predict the properties, composition and molecular structure of complex compounds during research. Such information helps to synthesize complex compounds with selected properties, composition and structure. Creating the basis of theoretical studies of the formation of complex compounds and the possibility of their practical application is one of the urgent problems of the chemistry of coordination compounds in the advanced period of modern science.

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References

Huang, Y., Peng, J. & Huang, X. Allylthiourea functionalized magnetic adsorbent for the extraction of cadmium, copper and lead ions prior to their determination by atomic absorption spectrometry. Microchim Acta 186, 51 (2019).

Aliyari, E., Fathi, A.A., Alvand, M. et al. β-Cyclodextrin-grafted magnetic graphene oxide nanocomposites in ultrasound-assisted dispersive magnetic solid-phase extraction for simultaneous preconcentration of lead and cadmium ions. Res Chem Intermed 47, 1905–1918 (2021).

Sorouraddin, S.M., Farajzadeh, M.A., Pinou, R. et al. Development of a reversed-phase dispersive liquid–liquid microextraction method for the extraction and preconcentration of lead and cadmium ions in some cosmetic products. Chem. Pap. 76, 2085–2092 (2022).

Nezhadali, A., Mohammadi, R., Akbarpour, M. et al. Application of the Taguchi Method and Central Composite Design for the Highly Selective and Efficient Extraction of Cu(II) ions from an Aqueous Solution Containing Mn(II), Co(II), Ni(II), Zn(II), Cu(II), and Pb(II) ions Mixture Using Benzyl Bis(thiosemicarbazone). Chemistry Africa 3, 1001–1008 (2020).

Sorouraddin, S.M., Parvizzad, K. & Farajzadeh, M.A. Development of a pH-induced dispersive solid-phase extraction method using folic acid combined with dispersive liquid–liquid microextraction: application in the extraction of Cu(II) and Pb(II) ions from water and fruit juice samples. ANAL. SCI. 39, 23–31 (2023).

Nazokat M., Fayzulla N., Abdulahat J. Flame retardant for cotton fabrics based on phosphate acid-urea polymer //Universum: химия и биология. – 2022. – №. 9-2 (99). – С. 53-56.

Muzaffarova N. S., Nurqulov F. N., Jalilov A. T. Pentaeritrit va ammofos asosida antipiren tayyorlash //Kimyo va tibbiyot: nazariyadan amaliyotgacha. 2022. – С. 77-80.

Muzaffarova N. S., Nurqulov F. N. Paxta matolari uchun azot va fosfor saqlovchi antipiren sintez qilish //Kimyo va tibbiyot: nazariyadan amaliyotgacha. – 2022. – С. 75-77.

Muzaffarova N., Toshtemirova N. Antipirenlar bilan ishlov berilgan tabiiy to ‘qimachilik materiallarning termik barqarorligini tadqiq etish //Theoretical and experimental chemistry and modern problems of chemical technology. – 2023. – Т. 1. – №. 01.

Nazokat M., Faizulla N., Abdulahat J. Synthesis of a new flame retardant, high content of phosphorus and nitrogen and its use in cotton fabrics //Universum: технические науки. – 2022. – №. 8-3 (101). – С. 59-62.

Muzaffarova, N., & Toshtemirova , N. Antipirenlar bilan ishlov berilgan tabiiy to‘qimachilik materiallarning termik barqarorligini tadqiq etish. Theoretical and Experimental Chemistry and Modern Problems of Chemical Technology, 1(01). Retrieved from https://ojs.qarshidu.uz/index.php/ch/article/view/36.

Muratov B.A, Turaev Kh. Kh, Umbarov I.A, Kasimov Sh.A, Nomozov A.K, "Studying of Complexes of Zn(II) and Co(II) with Acyclovir (2-amino-9-((2-hydroxyethoxy)methyl)-1,9- dihydro-6H-purine-6-OH),"Int. J of Eng. Trends and Tech. 2024; 72(1): 202-208. https://doi.org/10.14445/22315381/IJETT-V72I1P120.

Durdubaeva R., Beknazarov S., Nomozov A. Synthesis of 2, 4, 6-Triethanolimine-1, 3, 5-Triazine and its application as a corrosion inhibitor of carbon steel in 0.5 M H2SO4 solution //Science and Innovation. – 2022. – Т. 1. – №. 8. – С. 613-618.

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